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I have tried many linux distros, and I would have to say that Ubuntu will be the easiest for someone that, as I understand, is a "beginner" (since she wants to use an old PC). Ubuntu does not look too much windows, but if you help her and install a new theme, I am sure she will get a windows "feeling". Alternatively you could install kubuntu, but.... harder to navigate, I think. Go for ubuntu. More help for it on the net as well......
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