Just changed my PC too. In my case it was Windows 7 on 64, I found relatively little software for it but I have PS7 as well as CS4 installed and they both work fine. You should have 2 versions of Program Files in your c: or wherever. One with a number (#) behind it and the normal one. Look around for your Macromedia/Dreamweaver and try opening it directly from there or "run as admin" to see if it works...If it doesn't try installing them again and not just copying them from your older hdd
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