from the Baltic region the Estonia would be the best (and probably the only smart choice you can make) since it's small and has good business infrastructure if you think of doing business in there, especially online business. But over there is fucking cold in winter, so you should consider some other countries.
Poland and Chez Republic are bit better, since there are lots of hot chix to keep you warm during the cold months...
Spain is good too, but they are pretty poor and undeveloped country and are in debts so it could be risky. Also having long term problems with water supply and weather due the climate changes, but Barcelona is just way too cool city to live in, so you would probably had no problems adapting...
in general it all depends on what are you looking.
if you're looking for schools and hospitals, than Austria or Switzerland and UK would be the best places in Europe to live in, but also the most expensive ones....
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