Cats are awesome and of course they can pick their owners.
Cats have lots of personality. When you first meet a cat to adopt at a pet shop, shelter or spca alot of what you may like in a particular cat is the way they like you. You go for the one who looks you and purrs and is relaxed in your arms and the only way they can do this is if they like you first.
Definitely adopt your new stray friend.
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