It would be hard to tell without seeing the original site as well as the new results. If the site were strictly solid colors and you had the original PSD, it would be much easier obviously. If you don't have either, you are going to run into problems.
Your best bet is to take another screen cap into Photoshop this time and see if you can replicate the effect. Take note of what you are doing and either create an 'action' or write it down. Once you have the desired effect on your screen cap, you would have to replicate it for every individual image on your site.
Any decent designer should be able to replicate the before and after (from IrfanView) in Photoshop.
Hope this helps.
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