I am not an expert for buying an adult site, but what I' d make sure that there is clause, that the old owner is responsible for content which he might not hold the copyrights or which may be illegal up to the date of the transfer.
As you can't make sure he does give you a full list, I'd check the affiliates myself or use your own existing ones.
You might also choose a platform for an escrow-domain-transfer, if you don't know the webmaster personally.
Customers should be noticed for sure.
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