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Adwords can show you which keywords are relevant to your site I believe. I know you can also use negative keywords to force Google not to trigger your ad when someone types in a keyword, which I would assume if they do not trigger your ads, they will also not appear in your stats.
When you login to your google adwords campaign you should see a notice that a Google Adword consultant is available to help you out - take advantage of the service - its free and quite helpful. Just be careful - they of course always try to persuade you to increase you advertising budget. Increase your bid if you want but keep your monthly budget to something affordable otherwise you'll be in for an unpleasant surprise.
Good luck!
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