I would not be focusing so much of the Slovenian aspect, more about the person bringing these Slovenians to you and the reason why.
Unless you know the person well, it could be a risk, I would be asking how these Slovenian clients normally pay her.... and why she has the need to suddenly share the money with you by passing it through your business.
There are actually a few chargeback free methods of payment in Europe including for example paysafecard. That is available in Slovenia I believe but I have never had a sign up through that from there personally.
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