Go check out Sagrada Familia, it is absolutely stunning. I recommend doing the hop on, hop off bus tours of the city too, it's a great way to get around all the best sights. If you combine a 2 day pass, it works out cheaper and you can do all 3 routes, I think. I did it and it was great, you get to the Camp Nou and can take the tour then hop back on the bus and head to the next destination.
For night time, I like to hang out around the beach bars in Olimpico or on little side streets of La Rambla, there is tons of good food and cool little bars. Placa Reial is closer to the end of La Rambla but there is a couple of great restaurants in there that I ate at and usually some cool stuff going on.
If there is one City you will never be bored in, it is Barcelona. Have a great trip dude.
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