I don't think an affiliate program could stop you from doing whatever you want to with the money you receive from Revshare.
Will a program send the money to a charity for you? Probably not, but you can send it anytime you want.
As far as being able to advertise on your site that you are giving the revenue to charity, that you would have to check with each individual sponsor as the answer may differ depending on who is asking the question.
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